I have purchased 2 of the newly released LiTime 230Ah lithium batteries for my upgrade from AGM and have discovered an interesting weirdness that others might find interesting. Charging these batteries couldn't be simpler, just charge as fast as your converter will let you (up to 200A) until the battery voltage reaches 14.4V at which point the current drops off quite rapidly till the battery flips some kind of internal switch and doesn't accept any more charge.
What is weird is that once you've finished charging, the battery voltage reads low - around 12.8 to 13V. If you discharge the batteries at 5A or more for a minute or two, the battery voltage rises to the expected 13.3V (or more). I have to guess that this is due to the LiTime battery management system (BMS) that has to switch over from "don't accept any more charge" mode to "normal operation" mode.
This behavior, though weird, doesn't really matter if you're using just one battery (other than the battery appearing, voltage-wise, to be almost dead right after charging), but if you have 2 or more in parallel then the overall behavior may get quite bizarre: You'll charge both batteries up till they stop taking charge, then when the charger is no longer active, you start discharging. If you separated the batteries at this point, one would show a higher voltage than the other (as they are both in "don't accept any more charge" mode), and that battery will preferentially discharge. That will cause this battery to come out of "don't accept any more charge" mode and switch to "normal operation" mode, with a consequential increase in its battery voltage. The other battery won't discharge at all until the first battery's voltage drops low enough, at which point current starts to flow from the second battery and it comes out of "don't accept any more charge" mode and switches to "normal operation" mode too. Now the second battery will preferentially discharge till both batteries balance up. This isn't a problem, but if you separated the batteries for some reason when partially discharged, they might show radically different voltages across their terminals. Only downside that I can think of is that one battery may get way more exercise than the other, but as they each have 4000 discharge cycles available, it really doesn't matter.
I have no idea if this weird behavior is exhibited by other LiTime batteries, let alone other manufacturer's offerings (but I wouldn't be surprised...).
Roger and Sue Hill | 2020 T@B400 Boondock (Cryst@bel) | 2022 Land Rover Defender 110 - P400 | San Juan Island, WA
Comments
2020 nuCamp T@B 320S * Jeep Wrangler
Ken / 2023 Tab 400 “La Bolita” (23,000+ miles) / 2024 Toyota Sequoia
2024 - 3 Trips - 35 nights - 9 National Parks, 3 National Forests
2020 Tacoma TRD Off-Road
Ken / 2023 Tab 400 “La Bolita” (23,000+ miles) / 2024 Toyota Sequoia
2024 - 3 Trips - 35 nights - 9 National Parks, 3 National Forests
- I have 2 of these 230Ah LiTime batteries. Both exhibit the weird behavior detailed above.
- Judging by some web surfing, I'm not alone: Lots of others see the same issue as detailed here
- I discharged one of my batteries down to 10V, and it delivered 220Ah
- These are the first batteries from LiTime that feature low temperature charge protection. This prevents you from charging the battery below 0°C.
Quoting a reply from Litime to another owner who was inquiring about this behavior:This function provides more comprehensive protection for the battery and better performance of the battery system in two ways.
① Reduces voltage oscillations in the battery or system, maintains system performance and prevents abnormal system shutdown.
In situations where the battery needs to be connected to the charger for a long period of time, repeatedly turning on the battery after it has been fully charged can cause voltage oscillations in the battery or system (the battery voltage repeatedly cycles from resting down to charging up), which can affect system performance and even cause the system to shut down abnormally.
② Extend the life of the battery.
When a LiFePO4 battery is kept on high voltage charge for a long period (14.6V full charge voltage), its life span decreases relatively faster.
This function allows the battery to turn on the charge protection after a full charge, and then turn on the charge again after a certain discharge or resting voltage below a certain value, which can effectively circumvent the problems that may arise when the battery needs to be connected to the charger for a long time to charge without discharging.
After this battery is protected from overcharging,
the tested battery voltage (not the real voltage) will be lower than the real voltage.
To calculate the SOC (%), add 0.5V to 0.7V to the tested battery voltage.
We recommend that you take a small load (50W or above)and discharge it for 3-5 minute,
then leave it for 30 minutes before testing the voltage,
at which point the voltage should return to normal fully charged voltage(13.33V and above)
Here is some info about the BMS of the 12V 230Ah Plus battery for you:
Balance voltage for single cell:3.525±0.025V
Balance current for single cell:35±10mA
The balance module is working, it is recommended to charge with a small current, and the balancing time will be longer and more conducive to balancing.
Here are the recommended setting parameters for you:
Absorption Voltage:14.4V~14.6V
Float Voltage: 13.8V
Re-Bulk Voltage Offset: 13.0V
Tail Current:4.6A
Storage Voltage:50% SOC (see attached SOC form)
Bulk Time Limit: default
Re-bulk Current:default
Absorption Duration (Adaptive/Fixed): Adaptive
Maximum Absorption Time (for Adaptive)/Absorption Time (for Fixed):2h0m
Repeated Absorption:default
Others are default.
In contrast, we get 305ah from a 304ah lifepo4 battery discharging down to 11.0v at a continuous .33c (101a). If we discharged to 10v (not recommended) we'd get a tad more ah's. We'd get even more ah's if we discharged at a lower current, say .1c (30a).
Bottom line, lot of variables at play when doing a load-test.
If I was in the market to purchase a budget lifepo4 battery (or cells), I would only purchase from a source that offers a no-questions asked return policy. I would load-test the battery several times before the return window closes. It it fails to produce its rated ah capacity during any test, immediately return it. Assume the warranty is worthless---most generally are.
For those who'd rather not take a chance on in-series prismatic cells, they may want to take a closer look at the 12v 100ah Battleborn battery. Yes, I agree BB batteries are somewhat overpriced. However, there's a reason they cost more that goes beyond the BB name. The BB 12v 100ah lifepo4 battery uses 100+ cylindrical lifepo4 cells in a parallel/series arrangement. This cell arrangement costs more to produce, but it presents a distinct advantage vs. 4 prismatic cells in-series in terms of increased redundancy. In the event a few cells become weak or unbalanced it has much less effect on the overall ah output of the battery. The same cannot be said for 4 prismatic cells in series.
I am geeky enough to like to play around with these things on my Tab, however, at the end of the day, I just want to get out and not have to worry about my batteries. We recently took a 13 day trip to Big Bend NP and during that time the lowest the battery bank went down was to 63%. With abundant sunshine and the rooftop solar and a 220w external panel I was able to keep everything running like a champ. This included heavy inverter usage to power our Starlink and keep our electronics charged. To me the peace of mind that comes with this setup is worth the extra cost.
Ken / 2023 Tab 400 “La Bolita” (23,000+ miles) / 2024 Toyota Sequoia
2024 - 3 Trips - 35 nights - 9 National Parks, 3 National Forests
With 20-20 hindsight, this is what I should have done. My point remains, though: If your phone is your only method of connecting and you use it to set the Victron Multiplus II to "Inverter Only" and and then run your battery down to its low voltage disconnect, you have no simple way of recovering from this situation.
Ken / 2023 Tab 400 “La Bolita” (23,000+ miles) / 2024 Toyota Sequoia
2024 - 3 Trips - 35 nights - 9 National Parks, 3 National Forests
In any event, both @elbolillo and I replied to your Nov '23 inquiry:
https://tab-rv.vanillacommunity.com/discussion/17907/gfci-question-for-owners-with-multiplus-ii-3000w-inverter-charger
Which battery did you test? The "good" one or the battery with the strange/weird voltage readings?
Based on your load tests, hard to make any sense of the various voltage readings you've mentioned throughout this thread and a previous thread. I've monitored hundreds of lifepo4 charge/discharge cycles (most at cell level) over the last few years (using both DIY and off-the-shelf lifepo4 batteries). With very little variation, they all exhibited the same charging behavior when charged at the same C rate and voltage. Never seen a lifepo4 battery produce anywhere close to their ah rating when they exhibited a post-charge battery voltage as low as what you mentioned.
Have to say, that's a pretty serious con when you can't recommend connecting the LiTime batteries in parallel. How did you balance the two batteries before connecting them in parallel?
In any event, glad both batteries tested as well as they did. You seem to be experiencing a number of irregularities with your system. Has to be frustrating. Hopefully you'll get everything resolved soon.
2022 - 11 trips - 34 nights
2023 - 4 trips - 21 nights and counting
--------------------------------------------------
2018 BMW X5 xDrive35d (17 mpg towing avg)
2020 Toyota Tacoma TRD Off Road (10.9 mpg towing avg)
1) Why my lifepo4 batteries do not charge using the same charge profile as other lifepo4 batteries, and
2) Why my lifepo4 batteries do not function properly when connected in parallel.
"Not to worry about it" doesn't answer question #1.
A battery selector switch doesn't answer question #2.
Your constant, on-going use of "weird" to describe how your batteries operate is very, very telling. The above comments don't paint a rosy picture.
A key question for you is whether you're willing to settle for weird.
I'm wondering if that would be a benefit with LifeP04 cells that have a BMS. I'm guessing probably not since there is no way to disable the balancing function. Without a BMS the lower cells get balanced from the higher cells. This took many days to complete with my power supply.
I am thinking of purchasing two of the 230ah Litime batteries and will set my bulk and float voltage to 54.4v when using the trailer (my understanding is balancing is not very effective until voltage is at 3.4 VPC. I'll set the voltages lower when not using the trailer to extend their life